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Chiral diphosphites and diphosphoramidites derived from BINOL or diphenylprolinol are efficient ligands in asymmetric Rh-catalyzed olefin hydrogenation, provided the proper achiral backbone is chosen.

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Sep 5, 2003 · A density matrix formulation is used to investigate the transient NMR effects which occur when the rf field H 1 is changed discontinuously for a coupled AB system undergoing intramolecular chemical exchange. It is shown that the problem reduces to the solution of two matrix differential equations.

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